(4) 聚丙烯酰胺絮凝劑預處置普通占整個污泥處置費用較高的比例，因而，聚丙烯酰胺的優投加率的合理肯定對降低污泥預處置費用相當關鍵。對選擇聚丙烯酰胺的實驗辦法的研討已展開多年，包括比阻、CST值、污泥流變性、分別液粘度、活動電流等。The synthesis and process physical properties of AM polyacrylamide: PAM is prepared by direct reaction of acrylonitrile with water under the action of framework copper catalyst, and then dried by ion exchange polymerization. The process is as follows: catalyst: catalytic hydration CH2 = CHCN + H2 humidity CH2 = CHCONH2 polymerization nCH2 = CHCONH2 - initiator - CH2CHCONH2
Industrial uses of polyacrylamide: Polyacrylamide (PAM) has high molecular weight, good water solubility, adjustable molecular weight, and can introduce various ionic groups to obtain specific properties. Low molecular weight is an effective additive or stabilizer for dispersing materials. High molecular weight is an important flocculant. It can produce hydrophilic and water-insoluble gel, which has good adhesion to many groups of surface and dissolved substances. Because of the above properties, PAM is widely used in flocculation, thickening, drag reduction, glue imitation, bonding, scale inhibition and other fields.
Anionic polyacrylamide can be used in different molecular weights according to different uses and user's requirements for product performance.
In industrial wastewater treatment, especially for suspended particles, coarser, high concentration, positive charged particles, neutral and alkaline wastewater such as iron and steel plant wastewater, electroplating plant wastewater, metallurgical wastewater, coal washing wastewater and other wastewater treatment effect is very good.
In drinking water treatment. The water source of many Waterworks in our country is low in mud and high in mineral content, which is turbid. Although it has been treated by precipitation, it still can not meet the requirements. Flocculants are needed to make the water quality clear. Many waterworks use inorganic flocculants, but the amount of inorganic flocculants is large, resulting in poor effect of sludge increase. Anionic polyacrylamide acrylamide monomer was 0.012%. The molecular weight of anionic PAM was 12.5 million and the content of acrylamide monomer was 0.013%. The concentration of two kinds of PAM is 0.05%. They are used after refrigeration for 24 hours.
(1) PAM pretreatment sludge takes lOml sludge and puts it into a 300 ml beaker. Six-unit mixers are used to mix at 1130 RPM speed for 30 seconds, and then the PAM is added to the sludge quickly and quantitatively. The PAM is stirred at lOOrpm speed for 30 seconds, then the speed of the mixer is reduced to 20-30 rpm and the slow stirring speed is 60 seconds to promote flocculation. The specific resistance of pretreated sludge, capillary water absorption time (CST), the viscosity of filtrate and the viscosity of centrifuge were measured.
(2) The specific resistance is tested by Brinell funnel according to the test method proposed by Coackley. The diameter of Brinell funnel is 80 mm. The filter paper is made of 70 mm medium speed filter paper. The vacuum degree of the test is controlled to 0.01 MPa. The experiment was repeated three times to get the average value.
(3) In order to reduce specific resistance and improve sludge dewatering effect, sludge should be pretreated before sludge dewatering. Sludge pretreatment methods include freeze-thaw pretreatment, heat treatment, acid treatment, alkali treatment, lime pretreatment and polymer flocculant pretreatment. Polymer flocculant polyacrylamide (PAM) pretreatment is the most widely used pretreatment method at home and abroad.
(6)依據CST值變化肯定PAM最投加率與測定比阻得到的最投加率分歧。并且CST值與比阻之間存在線性相關關系，比阻值越大，CST值越大，因而能夠采用CST值來近似替代污泥比阻反映污泥的脫水性能。與比阻相比，cST值測定快速、煩瑣，不但適用于實驗室研討，還可用于消費現場，快速理解污泥脫水性能的變化，使操作人員及時調楚PAM投加率，儉省藥劑費。is used as flocculant, and the dosage is inorganic flocculant. One fiftieth of the flocculants, but the effect is several times to dozens of times that of inorganic flocculants. Especially the polyacrylamide produced by our company, the residual monomers have reached the food grade (less than 0.05%), close to the advanced level abroad, non-toxic, more suitable for the treatment of drinking water, and better for the use of organic pollutants polluted river water and anionic polyacrylamide.
Polyacrylamide is used to recover lost starch and distiller's grains in starch and alcohol factories. At present, the starch in the waste water discharged by many starch factories is very high. After discharging, it affects the environment, wastes resources, and adds PAM to make starch precipitate. The precipitate is filtered by pressure filter to become cake and can be used as feed. A large number of distillers'grains in the alcohol factories are processed by this process. A certain alcohol factory in Heilongjiang Province uses polyacrylamide as flocculant, which recycles the distillers' grains and obtains a great deal of experience. Economic benefits.
Polyacrylamide is used as water shutoff agent for profile control and water shutoff in Oilfield and oil displacement agent for tertiary oil recovery.
Polyacrylamide is used as paper-making additive. PAM is widely used in paper-making. It can be used as long fiber paper-making dispersant, wet and dry reinforcing agent, retention aid, filter aid and flocculant of paper-making wastewater.
The latest type of water treatment agent polyacrylamide, when treating sewage and water in many occasions, the combination of anionic polyacrylamide and cationic polyacrylamide has a very significant and synergistic effect than using one kind of ionic polyacrylamide alone. The ability of PAM to reduce surface tension is much greater than the ability of cations or anions existing alone under the same conditions. For the requirement of low surface tension, both anionic and cationic polyacrylamide need to be used at the same time. If they are used improperly, white precipitates will be produced and the effect of using them will be lost. PAM has the characteristics of amphoteric ions. It can complete the coordination of anions and cations. There is no precipitate on the surface. Especially, it is more convenient to use PAM as a flocculant because of the complex water quality or the changeable nature of water.
The sludge used in sewage pretreatment is taken from the sedimentation tank with Qiantang River water as its source of water, and PAC is used as a flocculant in the water plant. The sludge was naturally concentrated to a solid content of 2.7%-2.8%. The organic matter content in the sludge was 12.1%, SJ content was 52.1%, Al content was determined. The content was 20.2%. There are three types of PAM: cationic, anionic and nonionic. Non-ionic PAM dissolves slowly and is generally not used for sludge pretreatment. Therefore, only two representative cationic polyacrylamides and anionic polyacrylamides are selected in the experiment. The molecular weight of cationic PAM was 12 million and the content of
經過我們聚丙烯酰胺多年的研究，聚丙烯酰胺的絮凝性能與其溶液粘度直接相關。聚丙烯酰胺的粘度越高，性能越好，即聚丙烯酰胺的分子量越高。產品性能越好；如果其粘度因某些因素而降低，其絮凝性能將不可避免地下降。然而，聚丙烯酰胺溶液的粘度受許多其它因素的影響，例如溫度，濕度，溶解過程中的要弄清楚聚合氯化鋁與聚丙烯酰胺哪個是絮凝劑，首先我就要弄清楚混凝劑與絮凝劑的區別。混凝是指藥劑投加進水中水解后對廢水中膠體進行壓縮電雙分子層，使得脫穩、破乳凝聚形成絮體的一個過程。絮凝則是將各小的絮體，膠體顆粒進行吸附架橋，網捕沉淀，主要外表為粘結成大塊的絮體現運用，能夠選擇干粉顆粒狀聚丙烯酰胺，The classification obtained by the method is different. If the ionic type can be divided into Yin, non, amphoteric and cationic polyacrylamide, if according to the shape, it can be divided into four shapes: colloid, laxity, emulsion and dry powder. Which of these four forms is more suitable for us? The company gives you some suggestions. Next is our experience. I hope you will be interested.
In general, if we often use it, we can choose dry powder granular polyacrylamide. Because of its highest solid content, dry powder polyacrylamide is generally stored in dry and cool places for more than two years, but if mixed with solution, its storage time will be limited. Generally speaking, when the concentration of solution is 0.1%, non-ionic and anionic polyacrylamide will dissolve. The stability of cationic polyacrylamide solution depends on the concentration of the solution. For example, the more concentrated the solution is, the longer the storage time of 3%-5% solution is, but the 3%-5% solution can not be directly used to treat sewage. This solution needs to be diluted before use, and the PH value of cationic polyacrylamide solution is less than 5.5. Stability, if greater than 6.0, will be due to hydrolysis and failure, water medium dispersion polyacrylamide shelf life of six months.
Therefore, polyacrylamide is still a better choice of solids, can be used with the mix, do not cause waste.
Of course, we must pay attention to the conditions and taboos of preserving polyacrylamide. Polyacrylamide is more sensitive to iron ions, calcium ions and magnesium ions than anionic polymers. In particular, iron ions are catalysts for the chemical degradation of all polyacrylamide. Therefore, in the manufacture, handling and storage of polyacrylamide solutions, we must try to avoid iron ions entering and touching the solution. The equipment should be made of plastics, stainless steel, FRP or carbon steel with surface coating resin.由于它的固含量，一般情況下干粉聚丙烯酰胺在干燥、陰涼的當地是寄存二年以上的，但假如配成溶液的話，它的寄存時刻就有限了，一般說，溶液濃度為0.1%的時候，非離子與陰離子聚丙烯酰胺溶液不會超過一周的時刻，陽離子聚丙烯酰胺溶液則不會超過一天，而且溶液的穩定性與溶液的濃度有關，配的濃度越濃，例如3%——5%的溶液寄存時刻越長，但3%——5%的溶液不能直接去處理污水，這種在運用前需要稀釋，陽離子聚丙烯酰胺溶液PH值小于5.5的時后比較穩定，假如大于6.0的話，就會由于水解的原因而失效，水介質渙散型聚丙烯酰胺保質期為六個月。
